Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes.

نویسندگان

  • Qing-Zheng Yang
  • Daria Khvostichenko
  • John D Atkinson
  • Roman Boulatov
چکیده

In weakly coordinating solvents FeII meso-(N-methylimidazol-2-yl)porphine Fe exists as a stable dimer (Kd=50+/-30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.

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عنوان ژورنال:
  • Chemical communications

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2008